


Archive for October, 2009
Oct
26
The organic products used in jewelry are quickly affected by heat.’Pearls are completely spoiled; they turn brown and split. Amber burns with a camphor-like smell, giving off black fumes. Coral loses its color and decrepitates.
One other result of heating may be mentioned here, and that is the property which a few gem stones possess of emitting light, known as phosphorescence. This must not be confused with fluorescence. Pieces of quartz, when rubbed together in a dark room, give off a phosphorescent light, while heated fluorspar displays a very bright effect. Exposure to strong sunlight is sufficient to produce this effect in some minerals. Diamonds, especially yellow tinted specimens, are highly phosphorescent; apatite, a mineral occasionally cut as a gem stone, is slightly phosphorescent. Such effects may be more easily observed if the specimens are transferred quickly from the sunlight to a dark room.
The application of heat to improve or alter the color of stones needs considerable care, patience, and experience. Many stones are spoiled in such attempts to improve on nature and increase their commercial value. Zircon and the different varieties of quartz are perhaps the chief victims of man’s enterprise in this direction, and it is only the cost and the rarity of raw material thai limits greater experiment. But the artificial perfecting of precious stones may yet be one of the achievements of the future chemist or physicist.
Oct
22
Some brown zircons lose their color when heated, and become a brilliant white on cooling, at the same time increasing greatly in luster and brilliance. Other pale blue zircons may have their color intensified, which may or may not remain. Rubies and some other stones will change their color, which returns on cooling. Minute faults in some rubies and emeralds have been eliminated by very careful heating, but this is a risky procedure as the stones may crack. Some green tourmalines are rendered more brilliant by heating, while some aquamarines change to a darker blue shade. The same may be said of some golden beryls, which may be changed to a pale blue.
The majority of the carnelians we see on the market have been the subject of applied heat. Most were originally sards, the dark brown having been driven off, giving place to the attractive flesh color. Again, many of the brown and yellow transparent <|iiartz, the consistently misnamed “topaz,” are the product of 11 eating smoky quartz, while the yellow citrine and treacle brown “topaz quartz” are, in many instances, derived by heating ame-lliysts. At about 500° C, many, but not all, South American amethysts will change to a deep, brownish-red or orange color, sometimes approximating to a rich garnet shade. These stones are sold as Madeira Topaz, Spanish Topaz, or just “Topaz.”
A moderate heat is sufficient to make many amethysts and all (Urquoises fade in color. Further, if a stone contains water in its composition, it will be quickly affected. Opal is an example. This stone quickly cracks, loses its opalescence, and is entirely spoiled. Diamond will stand great heat, losing nothing but its superficial brilliancy, which can be regained by polishing. But at a very high temperature, it burns in air and oxygen, producing carbonic anhydride.
Some stones become clouded on heating, some fuse, while others are infusible. The degree of fusibility is important when making a qualitative analysis, and the results of submitting stones to the so-called “dry test,” which involves the use of a blow-pipe, are most necessary to the chemist who is seeking to ascertain the constituents of a given mineral. Some notes on the fusibility of gem stones under these conditions are given in a later chapter.

